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Salt Lake City — One problem in developing more efficient organic LED light bulbs and displays for TVs and phones is that much of the light is polarized in one direction and thus trapped within the light-emitting diode, or LED. University of Utah physicists believe they have solved this problem by creating a new organic molecule that is shaped like rotelle – wagon-wheel pasta – rather than spaghetti.
The rotelle-shaped molecule – known as a “pi-conjugated spoked-wheel macrocycle” —acts the opposite of polarizing sunglasses, which screen out glare reflected off water and other surfaces and allow only direct sunlight to enter the eyes.
The new study showed wagon-wheel molecules emit light randomly in all directions — a necessary feature for a more efficient organic LED (OLED). Existing OLEDs now in some smart phones and TVs use spaghetti-shaped polymers — chains of repeating molecular units — that emit only polarized light.
“This work shows it is possible to scramble the polarization of light from OLEDs and thereby build displays where light doesn’t get trapped inside the OLED,” said University of Utah physicist John Lupton, lead author of a study of the spoked-wheel-shaped molecules, which was published online Sept. 29 in the journal Nature Chemistry.
“We made a molecule that is perfectly symmetrical, and that makes the light it generates perfectly random,” he adds. “It can generate light more efficiently because it is scrambling the polarization. That holds promise for future OLEDs that would use less electricity and thus increase battery life for phones, and for OLED light bulbs that are more efficient and cheaper to operate.”
Lupton emphasizes the study is basic science, and new OLEDs based on the rotelle-shaped molecules are “quite a way down the road.”
He says OLEDs now are used in smart phones, particularly the Samsung Galaxy series; in pricey new super-thin TVs being introduced by Sony, Samsung, LG and others; and in lighting.
“OLEDs in smart phones have caught on because they are somewhat more efficient than conventional liquid-crystal displays like those used in the iPhone,” he says. “That means longer battery life. Samsung has already demonstrated flexible, full-color OLED displays for future roll-up smart phones.” Lupton says smart phones could produce light more efficiently using molecules that don’t trap as much light.
The large rotelle-shaped molecules also can “catch” other molecules and thus would make effective biological sensors; they also have potential use in solar cells and switches, he adds.
The study was funded by the Volkswagen Foundation, the German Chemical Industry Fund, the David and Lucille Packard Foundation and the European Research Council.
Lupton is a research professor of physics and astronomy at the University of Utah and also on the faculty of the University of Regensburg, Germany. He conducted the study with Utah physics graduate student Alexander Thiessen; Sigurd Höger, Vikas Aggarwal, Alissa Idelson, Daniel Kalle and Stefan-S. Jester of the University of Bonn; and Dominik Würsch, Thomas Stangl, Florian Steiner and Jan Vogelsang of the University of Regensburg.
Freeing Trapped Light
While conventional LEDs use silicon semiconductors, OLEDs in some of the latest cell phones and TVs are made with “pi-conjugated polymers,” which are plastic-like, organic semiconductors made of a chain of repeating molecular units.
“Conjugated polymers are a terrible mess,” Lupton says. “They now make only mediocre OLEDs, although people like to claim the opposite.”
For one thing, three-quarters of the light energy is in a state that normally is inaccessible — a problem addressed by another recent University of Utah study of OLEDs. Lupton says his study deals with another problem, which exists even if the other problem is overcome: the polarization of light in pi-conjugated polymers that leads to the “trapping” or loss of up to 80 percent of the light generated.
“Light is an oscillating field like a wave, and a wave moves in a certain direction,” Lupton says. “We call this direction of oscillation a polarization.”
Because polymers are long molecules like spaghetti, when an electrical current is applied to a polymer, “the electrons can only flow in one direction and that generates the light waves,” Lupton says. “Because those light waves only oscillate in one direction, the light can get trapped inside the OLED, which is a little bit like an optical fiber.”
That, he adds, is why even with the latest OLED smart phones, “your battery is dead in two days because the display uses a lot of the electricity.”